Development of Zr/ZrO<Subscript>2</Subscript> high temperature and high pressure sensors for <Emphasis Type="Italic">in-situ</Emphasis> measuring chemical parameters of deep-sea water

In order to in situ measure chemical parameters of deep-sea water and hydrothermal fluids at midocean ridge(MOR), it is necessary to use high temperature and high pressure chemical sensors.Developing new sensors is essential to measure in-situ pH and other chemical parameters(dissolved H2, dissolved H2S) of deep-sea water and hydrothermal fluids in a wide temperature range(2℃―400℃) at MOR vents.The YSZ(Yttria Stabilized Zirconia, 9%Y2O3) ceramic-based(HgO/Hg) chemical sensors possess excellent electrochemic...     

Introduction of fluorin into PBO polymer chains: Toward higher thermal stability and lower dielectric constant

A series of novel fluorinated benzoxazole polymers (6FPBO's) with high thermal stability and low dielectric constant were synthesized by copolymerization of 1,3-diamino-4, 6-dihydroxybenzene dihy-drochloride (DAR), 1,4-benzenedicarboxylic acid (PTA) and various amount of 4'4- (hexafluoroisopro-pylidene) bis (benzoic acid) (BIS-B-AF) in the medium of polyphosphoric acid (PPA). 6FPBO fibers were then obtained via dry-jet wet-spinning technique and characterized by means of Fourier transform infrared (FTIR) spectra, thermogravimetric analysis (TGA), single fiber tensile testing machine and scanning electron microscopy (SEM). FTIR spectrum of 6FPBO fibers indicated that the fluorine groups had been incorporated into PBO molecular chains successfully. TGA curves revealed that 6FPBO fibers possessed high thermal stability just as pure PBO fibers. Moreover, dielectric constant spectrum of 6FPBO exhibited that the polymers had low dielectric constant, especially in the range of high- frequency.     

Earth pressure balance control for EPB shield

This paper mainly deals with the critical technology of earth pressure balance (EPB) control in shield tunneling. On the assumption that the conditioned soil in the working chamber of the shield is plasticized, a theoretical principle for EPB control is proposed. Dynamic equilibrium of intake volume and discharge volume generated by thrust and discharge is modeled theoretically to simulate the earth pressure variation during excavating. The thrust system and the screw conveyor system for earth pressure cont...     

ZnO一维纳米结构在金属基底上的原位生长和表征

以Cu—Zn合金片为基底并提供Zn源,在含氧气氛中通过调控反应温度和氧偏压,采用热氧化法直接在Cu-Zn合金片上大面积可控地合成了多种形貌的ZnO一雏纳米材料薄膜（包括纳米带、纳米片、纳米梳和纳米线等）,采用多种分析方法对产物的形貌、结构进行了详细的表征,并对其相应的生长模型进行了讨论。结果表明,反应温度和氧偏压对ZnO纳米结构的生长至关重要,随着反应温度升高或氧含量的减少,气相Zn／O物种的偏压比增加,ZnO纳米结构尺寸变小。     

纳米聚丙烯酸酯微乳液改性纳米CaCO3研究

分别采用聚丙烯酸酯乳液和纳米级聚丙烯酸酯微乳液对纳米CaCO3进行改性,通过红外光谱分析、热重分析和扫描电镜分析研究改性纳米CaCO3的结构和性能。结果表明,改性后的纳米CaCO3由亲水疏油性变为亲油疏水性,纳米级聚丙烯酸酯微乳液与纳米CaCO3粒子表面发生了化学反应,并包覆到纳米CaCO3粒子表面。     

基于Visual C＋＋的虚拟PLC仿真软件开发

为了能够不依托于实际硬件可编程控制器来实现基于可编程控制器的控制,研究了利用Visual C++开发的虚拟可编程控制器仿真软件.研究了基于面向对象方法的梯形图的绘制技术,以及基于二叉树的梯形图向指令表的转换问题.十字路口交通灯的虚拟仿真表明,该虚拟可编程控制器仿真软件可以用于可编程控制器的实训和实验教学.     

盐酸二甲双胍测定研究进展

盐酸二甲双胍是目前广泛用于临床医学的双胍类降糖药。本文综述了目前分析测定药剂中和血液中盐酸二甲双胍的各种方法,并对今后的发展提出了展望。     

混合溶剂在高分子膜中的传递模型

以单溶剂在高分子膜中的蠕变传递模型为基础,通过考虑溶剂间的耦合作用对溶剂在高分子膜中传递过程的影响,建立了混合溶剂在高分子膜中传递的蠕变模型.对模型参数进行了数值模拟研究,并使用该模型关联了吸收实验曲线.计算结果显示模型具有一定的预测功能.     

非下采样Contourlet域融合和参数化内核图割的SAR图像无监督水灾变化检测

目的 基于非下采样Contourlet变换（NSCT）融合策略可以有效地抑制背景信息增强变化区域的信息。但是融合后图像具有复杂的统计特征,传统的基于统计特征的变化检测难以实现。基于参数化内核图割的遥感图像分割不受统计特征的限制。为此提出了一种基于NSCT融合和参数化内核图割的SAR图像无监督水灾变化检测新算法。方法 将均值比差异图像和对数比差异图像采用基于NSCT的融合算法进行融合,将融合后的差异图像采用参数化内核图割算法进行前景/背景的分割,得到最终的变化检测结果。结果 融合后的差异图像利用前两种差异图像的互补信息提高了变化检测精度。算法不受统计模型限制,不需要先验知识,适用性强。结论 实验结果表明,本文算法的检测精度优于传统的变化检测方法。     

Gabor小波和改进LBP的零件表面粗糙度识别

目的 为了提取零件表面图像的纹理特征并对其表面粗糙度分类识别,有效提高识别的正确率,提出了联合Gabor小波和改进局部二值模式(LBP)的纹理特征提取方法。方法 针对传统LBP算子忽略了邻域内灰度差幅值特征的问题,提出了M_LBP(magnitude considered LBP)算子。采用Gabor小波对零件表面图像滤波,并计算各子图像 Gabor幅值特征GMM(Gabor magnitude maps)。应用M_LBP算子计算各GMM的M_LBP特征谱,进而构造得到零件表面图像的纹理特征向量,最后通过KNN(K-nearest neighbor)算法对零件粗糙度分类识别。结果 本文提出的算法有效细化了表面图像纹理特征,对粗糙度差别为0.2 μm的零件识别准确率达到98%,远高于利用传统LBP算子提取的纹理信息的识别准确率。结论 本文提出了一种有效细化LBP纹理特征的M_LBP算子,并通过与Gabor小波的结合,突破了传统LBP算子尺度、方向单一,幅值信息被忽略的局限性,能实现较高精度的粗糙度识别。